The five periodic properties we will be studying are Ionization
energy, electron affinity, electro-negativity, atomic radius and ionic
radius. Let's take them one at a time.
Ionization Energy
Ionization Energy is defined as the energy required to remove an
electron from a neutral atom. This energy is sometimes measured in terms
of the voltage necessary to remove the electron which is why it is
sometimes called ionization potential (potential is the fancy physics
term for voltage). This process results in a positive ion.
Electron Affinity
Electron Affintiy is the amount of energy released when an
electron is added to a neutral atom, making a negative ion. If it is not
immediately obvious why adding an electron should release energy,
remember the definition of potential energy; potential energy involves
an attractive force and a distance. When the electron enters the atom it
is coming from far away and the distance to the nucleus is getting
smaller. As the distance gets smaller, the potential energy gets
smaller. Since energy can't be destroyed, it must be leaving. This is
essentially the same explanation that Bohr gave for how the Hydrogen
tube gave off light, only in a much more extreme version; here the
electron is falling, not from an upper level of the atom, but from
completely outside the atom.
Electronegativity
Electronegativity is the force with which one atom pulls on the electrons of another atom in a
covalent bond. Remember that a covalent bond is not a sharing of electrons, but rather a tug-of-war for electrons.
Atomic Radius
Atomic radius is the radius of an atom. This can be measured in
various ways and is sometimes described as the covalent radius (half of
the distance between two nuclei in a covalent bond). For our purposes,
it is simply a measure of how big the atom is.
Ionic Radius
Ionic radius is the radius of the ion that is isoelectronic with
the nearest noble gas. This means that as you go across the periodic
table from the left to the right the ions start with positive charges
and then in the middle of the table (around C in the second row) switch
to negative ions. Ionic radius is simply a measure of the size of these
ions. That means that on the second row (period) of the table we are
talking about Li
+1, Be
+2, B
+3, C
+4 (or C
-4), N
-3, O
-2, and F
-1.
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